91.
$$20\,mL$$ of $$0.2\,M\,NaOH$$ are added to $$50\,mL$$ of $$0.2\,M\,C{H_3}COOH\left( {{K_a} = 1.8 \times {{10}^{ - 5}}} \right)$$ the $$pH$$ of the solution is
The characteristics of the given solutions are :
$$NaCl\,\, - $$ neutral solution
$$N{H_4}Cl\,\, - $$ slightly acidic due to the following reaction
$$NH_4^ + + {H_2}O \rightleftharpoons N{H_4}OH + {H^ + }$$
$$NaCN\,\, - $$ slightly alkaline due to the following reaction
$$C{N^ - } + {H_2}O \rightleftharpoons HCN + O{H^ - }$$
$$HCl\,\, - $$ highly acidic
The $$pH$$ of the solution will follow the order highly acidic < slightly acidic < neutral < slightly alkaline i.e. $$HCl < N{H_4}Cl < NaCl < NaCN$$
93.
What will be the $${H^ + }\,ion$$ concentration in a solution prepared by mixing $$50\,mL$$ of $$0.20\,M\,NaCl,25\,mL$$ of $$0.10\,M\,NaOH$$ and $$25\,mL$$ of $$0.30\,N\,HCl?$$
94.
The values of $${K_{{p_1}}}$$ and $${K_{{p_2}}}$$ for the reactions
$$\eqalign{
& X \rightleftharpoons Y + Z\,\,\,...{\text{(i)}} \cr
& {\text{and}}\,A \rightleftharpoons 2\,B\,\,\,...{\text{(ii)}} \cr} $$
are in ratio of 9 : 1. If degree of dissociation of $$X$$ and $$A$$ be equal, then total pressure at equilibrium (i) and (ii) are in the ratio
95.
A weak acid, $$HA,$$ has a $${K_a}$$ of $$1.00 \times {10^{ - 5}}.$$ If $$0.100$$ $$mole$$ of this acid is dissolved in one litre of water, the percentage of acid dissociated at equilibrium is closest to
Blood is an example of buffer solution, which contains serum protein, so its $$pH$$ does not change appreciably by adding small amount of an acid or a base to it.
97.
For a reaction, $${A_x}{B_y} \rightleftharpoons x{A^{y + }} + y{B^{x - }},{K_{sp}}$$ can be represented as
A.
$${\left[ {{A^{y + }}} \right]^x}{\left[ {{B^{x - }}} \right]^y}$$
B.
$${\left[ A \right]^y}{\left[ B \right]^x}$$
C.
$${\left[ A \right]^x}{\left[ B \right]^y}$$
D.
$${\left[ A \right]^{x + y}}{\left[ B \right]^{x - y}}$$
NOTE: A buffer is a solution of weak acid and its salt
with strong base and vice versa.
$$HCl$$ is strong acid and $$NaCl$$ is its salt with strong base.
$$pH$$ is less than 7 due to $$HCl.$$