1.
The average translational kinetic energy of $${O_2}$$ (relative molar mass 32) molecules at a particular temperature is $$0.048\,eV.$$ The translational kinetic energy of $${N_2}$$ (relative molar mass 28) molecules in $$eV$$ at the same temperature is
Average translational kinetic energy of an ideal gas molecule is $$\frac{3}{2}\,kT$$ which depends on temperature only. Therefore, if temperature is same, translational kinetic energy of $${O_2}$$ and $${N_2}$$ both will be equal.
2.
Pressure versus temperature graph of an ideal gas of equal number of moles of different volumes are plotted as shown in figure. Choose the correct alternative
A.
$${V_1} = {V_2},{V_3} = {V_4}\,{\text{and}}\,{V_2} > {V_3}$$
B.
$${V_1} = {V_2},{V_3} = {V_4}\,{\text{and}}\,{V_2} < {V_3}$$
From ideal gas equation $$PV = \mu RT$$
⇒ Slope of $$P.T$$ curve $$\frac{P}{T} = \frac{{\mu R}}{V}$$
$$ \Rightarrow {\text{Slope}} \propto \frac{1}{V}$$
It means line of smaller slope represent greater volume of gas.
For the given problem figure
Point 1 and 2 are on the same line so they ill represent same volume i.e. $${V_1} = {V_2}$$
Similarly point 3 and 4 are on the same line so they will represent same volume i.e. $${V_3} = {V_4}$$
Also slope of line 1-2 is less than 3-4.
Hence $$\left( {{V_1} = {V_2}} \right) > \left( {{V_3} = {V_4}} \right)$$
3.
Two vessels separately contain two ideal gases $$A$$ and $$B$$ at the same temperature, the pressure of $$A$$ being twice that of $$B.$$ Under such conditions, the density of $$A$$ is found to be 1.5 times the density of $$B.$$ The ratio of molecular weight of $$A$$ and $$B$$ is
$$\eqalign{
& {\rho _A} = 1.5\,{\rho _{B}}\,\,\,\,{\rho _B} \cr
& {\rho _A} = 2{\rho _B}\,\,\,\,\,\,\,{p_B} \cr} $$
According to ideal gas equation, we have
Pressure, $$p = \frac{{\rho RT}}{M},$$ where $$M$$ is molecular weight of ideal gas.
Such that, $$\frac{p}{\rho } = \frac{{RT}}{M}$$
$$ \Rightarrow M = \frac{{\rho RT}}{P}$$
where, $$R$$ and $$T$$ are constants.
So, $$M \propto \frac{\rho }{p} \Rightarrow \frac{{{M_A}}}{{{M_B}}} = \frac{{{\rho _A}}}{{{\rho _B}}} \times \frac{{{p_B}}}{{{p_A}}}$$
$$ = 1.5 \times \frac{1}{2} = 0.75 = \frac{3}{4}$$
4.
At very high temperatures vibrational degrees also becomes active. At such temperatures an ideal diatomic gas has a molar specific heat at constant pressure, $${C_p}$$ is
$$\frac{{K.E.}}{{vol}} = \frac{3}{2}P.$$
Here $$P$$ is constant
8.
Three closed vessels $$A,B$$ and $$C$$ are at the same temperature $$T$$ and contain gases which obey the Max wellian distribution of velocities. Vessel $$A$$ contain only $${O_2},B$$ only $${N_2}$$ and $$C$$ a mixture of equal quantities of $${O_2}$$ and $${N_2}.$$ If the average speed of the $${O_2}$$ molecules in vessel $$A$$ is $${v_1}$$ that of the $${N_2}$$ molecules in vessel $$B$$ is $${v_2},$$ the average speed of the $${O_2}$$ molecules in vessel $$C$$ is
A.
$$\frac{{{v_1} + {v_2}}}{2}$$
B.
$${{v_1}}$$
C.
$${\left( {{v_1} \cdot {v_2}} \right)^{\frac{1}{2}}}$$
All three vessels are at same temperature. According to Maxwell's distribution of speed, average speed of molecules of a gas $$v \propto \sqrt T .$$
∴ The velocity of oxygen molecules will be same in $$A$$ as well as $$C$$ where $$M$$ is the mass of an oxygen molecule.
9.
At constant volume temperature is increased, then
A.
collision on walls will be less
B.
number of collisions per unit time will increase
C.
collisions will be in straight lines
D.
collisions will not change
Answer :
number of collisions per unit time will increase
On raising the temperature, the average velocity of the gas molecules increases. As a result of which more molecules collide with the walls or number of collisions per unit time will increase.
10.
The molecules of a given mass of a gas have $$r.m.s.$$ velocity of $$200\,m{s^{ - 1}}$$ at $${27^ \circ }C$$ and $$1.0 \times {10^5}\,N{m^{ - 2}}$$ pressure. When the temperature and pressure of the gas are respectively, $${127^ \circ }C$$ and $$0.05 \times {10^5}\,N{m^{ - 2}},$$ the $$r.m.s.$$ velocity of its molecules in $$m{s^{ - 1}}$$ is: